NA NA NA NA . . .
So, since Super-Villains aren't in the Line-Up, it's irrelevant.
Not quite... The Crisis Super-Villains United places a Super-Villain in the Line-Up. When this S-V is defeated, it is removed from game like the other S-V's and, if Crisis Black Canary defeats this S-V, that player does not get you use her ability to put it on the bottom of their deck.